This was discussed recently on twitter. An answer that came through strongly was that Digital Archivist roles shouldn't exist. Instead archivist roles should include digital capabilities and functions.
I suspect there will be a transition period before we can reach that goal (assuming we want to). In the interim some things that might be useful qualifications for digital archivists would be:
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Scripting/programming ability
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Experience using, developing, documenting or troubleshooting open source software
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Experience with obsolete software and hardware
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Comfort with metadata and detailed structured documentation
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Ability to communicate the value of digital preservation/digital archiving
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Experience migrating data
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Experience performing database migration
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Master data management experience
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Business Intelligence experience/reporting
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Experience with virtualization (or emulation)
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Experience with digital forensics
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Experience with programmatic pattern matching
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Interest in old digital content